Had a similar problem with a room, and had lots of complex solutions offered to solve it.
In the end we simply put an electric programmable radiator in there. Problem solved. Simple. Can set the desired temperature and times you want it on, all in the inbuilt programmer.
Does it cost anything to use? Yes it uses electricity. But pretty cost effective in my opinion and it has the main advantage which is it works?
We used one of these. Easily installed by any electrician.
https://www.dimplex.co.uk/product/q-...ctric-radiator
Online calculator for radiator output needed for a room.
https://www.dimplex.co.uk/room-heating-calculator