If my GCSE maths still serves me well I will attempt a solution.
So to answer your question:
If your refill cost £23 you bought (£23/£1.118) 20.57 litres of petrol which is 4.52 gallons ( 1 litre = 0.22 gallon)
You did 263 miles / 4.52 gallons = 58.2 MPG.
The car says 64.2 MPG - actual 58.2MPG = 6.0MPG that wasn't achieved
6MPG/58.2MPG x 100/1 = 10.3% overestimation.
However, what you really want to know is what percentage of the displayed MPG is really delivered. In this case you need to divide 58.2/64.2 x 100/1 = 90.7%.
This now leads us to how do I look at my dash and work out the actual MPG = whatever it tells you x 0.907.