Google-image “central heating s plan wiring diagram” - look at the very first image from Flameport.com
The S-plan diagram will show you the basics.
https://www.flameport.com/electric/c...ing_S_plan.cs4
You can see that the timer sends the signal to the Boiler and Pump via:
1. The Room thermostat,
2. The CH Zone valve.
Best test is using a voltmeter on the following points, while the heating is ‘in demand’
This will show you how far the signal is getting.
a. Input to the thermostat (4 on the connector strip )
b. Between thermostat and CH zone valve (5 on the connector strip)
c. Between the CH zone valve and the Boiler/pump (1 on the connector strip)
Hopefully yours will be wired up similar, but it isn’t difficult to figure out.
It could well be the thermostat, but - it is the zone valve that heats up fairly quickly when the CH comes on (after heat/flow are established), so may affect the switch in the valve motor head - causing it to open (if it is intermittent faulty)
Remember you are dealing with mains voltage (live to neutral)