I know someone that has one. On his, you can receive calls on either number but when you dial out or use data, you chose which one you use. You can’t have one number on both sims. You can do as you suggest and have your main number on contract that diverts to a PAYG sim on the network you feel works in areas where the main one doesn’t.
Where are you getting poor reception - is it a fixed location? In my house as well as my sisters, reception is patchy but on an iPhone you can set up WiFi calling as long as you can connect to the WiFi - it’s seamless and does it automatically once you have set it up in the settings. Last month we were staying in a remote cottage in the Peak District. No phone signal whatsoever but the cottage had WiFi so making and receiving calls and texts were perfect once we were logged on to the WiFi. You only need to set it up once and it will work automatically wherever the phone is on a WiFi network and the phone signal is poor or non-existant.